Absorptive curtains and Radio Drama studio experience.
For recording radio drama we used to use a large studio similar in size to your living area, but without the rounded corner. Using VERY heavy curtains suspended from the ceiling we used to achieve a very good separation between the "live" end with it's wooden floor, and the "soft" area with a carpeted area. We then had to use plexiglass reflective screens to face the curtain into the "live" area!
OK, now this was to create two differing acoustics for actors to work in but I think that there are areas in common with what you want to do. The floor to ceiling curtains we had to use to achieve a sufficient amount of sound absorption were very heavy. The outer curtain was a very heavy lined velvet cotton drape and there was an inner separate curtain as a fireproof liner. These worked incredibly well but cost a small fortune.
I think that no matter which seating arrangement you use, you may need floor to ceiling drapes as heavy as you can afford to retain a low reverberation time in the listening area as the reflections from the hard plaster will need absorbing before they can reflect again. If you were to curtain off the reflective window that would help enormously too.
One advantage of such a large room is that the bass performance should be very smooth, the curtains absorptive effect diminishes with frequency.
Once the curtains are in place you could juggle with the position of speakers and listening position before making them permanent.
Paul
"If all else fails, read the instructions"